Prep the Pork: Pat the pork chops completely dry with paper towels. This is crucial for getting a good sear. Season generously on all sides, including the fatty edge, with salt and pepper.
Heat the Skillet: Place a large skillet over medium-high heat. Add the olive oil and heat until it begins to shimmer, but not smoke.
Sear the Chops: Carefully place the pork chops in the hot skillet, ensuring they don't touch. Sear for 4-6 minutes without moving them, until a deep golden-brown crust forms on the bottom.
Flip and Add Aromatics: Flip the pork chops. Add the butter, smashed garlic cloves, and thyme sprigs to the pan.
Baste and Finish Cooking: As the butter melts, tilt the pan and use a spoon to baste the chops with the fragrant, melted butter. Continue to cook for another 4-6 minutes. For perfect results, use an instant-read thermometer inserted into the thickest part of the chop (not touching the bone). Remove the chops from the skillet when the internal temperature reaches 140−145
∘
F (60−63
∘
C).
Rest: Transfer the pork chops to a cutting board or plate and let them rest for 5 minutes. The internal temperature will continue to rise slightly. This step is essential for juicy pork.
Serve: Serve whole or sliced, spooning any remaining pan sauce over the top.